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Direct Trifluoromethylation of the CH Bond

被引：282
作者：
Liu, Hui [1 ]
Gu, Zhenhua [2 ]
Jiang, Xuefeng [1 ]
机构：
[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 04期
基金：
中国博士后科学基金;
关键词：
catalysis; CH activation; copper; palladium; trifluoromethylation; CATALYZED OXIDATIVE TRIFLUOROMETHYLATION; ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION; PD(II)-CATALYZED ORTHO-TRIFLUOROMETHYLATION; CARBON-HYDROGEN BONDS; ROOM-TEMPERATURE; BORONIC ACIDS; MEDIATED TRIFLUOROMETHYLATION; HETEROAROMATIC-COMPOUNDS; H TRIFLUOROMETHYLATION; PHOTOREDOX CATALYSIS;
D O I：
10.1002/adsc.201200764
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Trifluoromethylation meets CH activation: after transition metal-catalyzed trifluoromethylation became more and more popular, trifluoromethylation via CH activation is now emerging as the latest attraction. Several pioneering examples and their mechanisms are discussed in this review.
引用
收藏
页码：617 / 626
页数：10
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