In situ generation of hydrogen for continuous hydrogenation reactions in high temperature water

被引：33

作者：

Garcia-Verdugo, E ^{[1
]}

Liu, ZM ^{[1
]}

Ramirez, E ^{[1
]}

Garcia-Serna, J ^{[1
]}

Fraga-Dubreuil, J ^{[1
]}

Hyde, JR ^{[1
]}

Hamley, PA ^{[1
]}

Poliakoff, M ^{[1
]}

机构：

[1] Sch Chem, Nottingham NG7 2RD, England

来源：

GREEN CHEMISTRY | 2006年 / 8卷 / 04期

关键词：

D O I：

10.1039/b515470g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermal decomposition of HCO2H or preferably, HCO2X (X = Na or NH4) can be used to generate H-2 for the continuous hydrogenation of aromatic and cyclic aldehydes, ketones and nitroaromatics in high temperature pressurised water (HTPW). This means that hydrogenation reactions can be carried out in exactly the same equipment as has previously been used for selective oxidation in HTPW, thus facilitating relatively simple application of these reactions for non-specialists.

引用

页码：359 / 364

页数：6

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