An alternative procedure for the synthesis of [5]- and [7]carbohelicenes

被引：42

作者：

El Abed, R

Ben Hassine, B

Genêt, JP

Gorsane, M

Marinetti, A

机构：

[1] Fac Sci Monastir, Lab Synth Organ Asymetr & Catalyse Homogene, Monastir 5019, Tunisia

[2] Ecole Natl Super Chim Paris, Lab Synth Select Organ & Prod Nat, UMR 7573, F-75231 Paris 06, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 2004卷 / 07期

关键词：

helicenes; heck reaction; palladium; photocyclisation; synthetic methods;

D O I：

10.1002/ejoc.200300470

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Bromo[5]helicene derivatives and substituted [7]helicenes have been prepared through a synthetic sequence relying on Heck-type and photocyclodehydrogenation reactions. This procedure provides a new, versatile and efficient approach to helicene derivatives, ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

引用

收藏

页码：1517 / 1522

页数：6

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