MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification

被引：239

作者：

Canivet, Jerome ^{[1
]}

Aguado, Sonia ^{[1
]}

Schuurman, Yves ^{[1
]}

Farrusseng, David ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, Inst Rech Catalyse & Environm Lyon IRCELYON, F-69626 Villeurbanne, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 11期

基金：

欧盟第七框架计划;

关键词：

METAL-ORGANIC FRAMEWORKS; SURFACE ORGANOMETALLIC CHEMISTRY; NICKEL-COMPLEXES BEARING; HIGHER OLEFINS PROCESS; HETEROGENEOUS CATALYSIS; METALLOCENE CATALYSTS; DIIMINE CATALYSTS; OLIGOMERIZATION; POLYMERIZATION; SILICA;

D O I：

10.1021/ja312120x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal-organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is found using the Ni@(Fe)MIL-101 catalyst than reported for molecular nickel diimino complexes.

引用

页码：4195 / 4198

页数：4

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