A new heterogeneous catalyst for epoxidation of alkenes via one-step post-functionalization of IRMOF-3 with a manganese(II) acetylacetonate complex

被引:123
作者
Bhattacharjee, Samiran [1 ]
Yang, Da-Ae [1 ]
Ahn, Wha-Seung [1 ]
机构
[1] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea
关键词
METAL-ORGANIC FRAMEWORKS; OLEFINS; CYCLOHEXENE; OXIDATION; STORAGE; SILICA; MCM-41;
D O I
10.1039/c1cc00069a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A manganese(II) acetylacetonate complex has been immobilized to the metal-organic framework IRMOF-3 through a one-step post-synthetic route for the first time, providing an effective and recyclable heterogeneous catalyst for epoxidation of alkenes.
引用
收藏
页码:3637 / 3639
页数:3
相关论文
共 34 条
[1]   Zeolite-like metal-organic frameworks as platforms for applications:: On metalloporphyrin-based catalysts [J].
Alkordi, Mohamed H. ;
Liu, Yunling ;
Larsen, Randy W. ;
Eubank, Jarrod F. ;
Eddaoudi, Mohamed .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (38) :12639-+
[2]   High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].
Banerjee, Rahul ;
Phan, Anh ;
Wang, Bo ;
Knobler, Carolyn ;
Furukawa, Hiroyasu ;
O'Keeffe, Michael ;
Yaghi, Omar M. .
SCIENCE, 2008, 319 (5865) :939-943
[3]   Comparison of the epoxidation of cyclohexene, dicyclopentadiene and 1,5-cyclooctadiene over LDH hosted Fe and Mn sulfonato-salen complexes [J].
Bhattacharjee, S ;
Anderson, JA .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 249 (1-2) :103-110
[4]   Synthesis and application of layered double hydroxide-hosted catalysts for stereoselective epoxidation using molecular oxygen or air [J].
Bhattacharjee, S ;
Dines, TJ ;
Anderson, JA .
JOURNAL OF CATALYSIS, 2004, 225 (02) :398-407
[5]   Ring-Opening Reactions within Porous Metal-Organic Frameworks [J].
Britt, David ;
Lee, Chain ;
Uribe-Romo, Fernando J. ;
Furukawa, Hiroyasu ;
Yaghi, Omar M. .
INORGANIC CHEMISTRY, 2010, 49 (14) :6387-6389
[6]   C-H activation of methyl vinyl ketone in Ir(acac){η2-CH2=CHC(O)CH3}(PCy3) [J].
Castarlenas, R ;
Esteruelas, MA ;
Martin, M ;
Oro, LA .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 564 (1-2) :241-247
[7]   Silica gel anchored chiral Mn(III)salen complexes for enantioselective epoxidation of unfunctionalised olefins [J].
Choudary, BM ;
Chowdari, NS ;
Kantam, ML ;
Santhi, PL .
CATALYSIS LETTERS, 2001, 76 (3-4) :213-218
[8]   Engineering Metal Organic Frameworks for Heterogeneous Catalysis [J].
Corma, A. ;
Garcia, H. ;
Llabres i Xamena, F. X. L. I. .
CHEMICAL REVIEWS, 2010, 110 (08) :4606-4655
[9]   Metal-Organic Frameworks as Efficient Heterogeneous Catalysts for the Regioselective Ring Opening of Epoxides [J].
Dhakshinamoorthy, Amarajothi ;
Alvaro, Mercedes ;
Garcia, Hermenegildo .
CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (28) :8530-8536
[10]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472