High performance hybrid solar cells sensitized by organolead halide perovskites

被引：622

作者：

Cai, Bing ^{[1
,2
]}

Xing, Yedi ^{[1
]}

Yang, Zhou ^{[1
]}

Zhang, Wen-Hua ^{[1
]}

Qiu, Jieshan ^{[2
]}

机构：

[1] Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Dalian Univ Technol, Carbon Res Lab, Liaoning Key Lab Energy Mat & Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2013年 / 6卷 / 05期

基金：

中国国家自然科学基金;

关键词：

ALL-SOLID-STATE; LOW-COST; EFFICIENCY; LAYER; IMPROVEMENT; FILMS; FIELD;

D O I：

10.1039/c3ee40343b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid state hybrid solar cells with hybrid organolead halide perovskites (CH3NH3PbBr3 and CH3NH3PbI3) as light harvesters and p-type polymer poly[N-9-hepta-decanyl-2,7-carbazole-alt-3,6-bis-(thiophen-5-yl)-2,5-dioctyl-2,5-di-hydropyrrolo[3,4-]pyrrole-1,4-dione] (PCBTDPP) as a hole transporting material were studied. The CH3NH3PbBr3-sensitized hybrid devices display an outstanding open circuit voltage (V-oc) of similar to 1.15 V, and the CH3NH3PbI3-based cells exhibit a power conversion efficiency (PCE) of similar to 5.55% along with high stability. The present results show that PCBTDPP is superior to the model p-type polymer P3HT as a HTM in these hybrid solar cells to achieve remarkably high Voc and high PCE. The possible mechanisms have been suggested.

引用

页码：1480 / 1485

页数：6

共 46 条

[1] Influence of Ion Induced Local Coulomb Field and Polarity on Charge Generation and Efficiency in Poly(3-Hexylthiophene)-Based Solid-State Dye-Sensitized Solar Cells [J].

Abrusci, Agnese ;

Kumar, R. Sai Santosh ;

Al-Hashimi, Mohammed ;

Heeney, Martin ;

Petrozza, Annamaria ;

Snaith, Henry J. .

ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (13) :2571-2579

[2] Role of Majority and Minority Carrier Barriers Silicon/Organic Hybrid Heterojunction Solar Cells [J].

Avasthi, Sushobhan ;

Lee, Stephanie ;

Loo, Yueh-Lin ;

Sturm, James C. .

ADVANCED MATERIALS, 2011, 23 (48) :5762-+

[3] Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies [J].

Bach, U ;

Lupo, D ;

Comte, P ;

Moser, JE ;

Weissörtel, F ;

Salbeck, J ;

Spreitzer, H ;

Grätzel, M .

NATURE, 1998, 395 (6702) :583-585

[4] Engineering Organic Sensitizers for Iodine-Free Dye-Sensitized Solar Cells: Red-Shifted Current Response Concomitant with Attenuated Charge Recombination [J].

Bai, Yu ;

Zhang, Jing ;

Zhou, Difei ;

Wang, Yinghui ;

Zhang, Min ;

Wang, Peng .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (30) :11442-11445

[5] High-Performance Nanostructured Inorganic-Organic Heterojunction Solar Cells [J].

Chang, Jeong Ah ;

Rhee, Jae Hui ;

Im, Sang Hyuk ;

Lee, Yong Hui ;

Kim, Hi-jung ;

Seok, Sang Il ;

Nazeeruddin, Md K. ;

Gratzel, Michael .

NANO LETTERS, 2010, 10 (07) :2609-2612

[6] Direct Growth of Metal Sulfide Nanoparticle Networks in Solid-State Polymer Films for Hybrid Inorganic-Organic Solar Cells [J].

Dowland, Simon ;

Lutz, Thierry ;

Ward, Alexander ;

King, Simon P. ;

Sudlow, Anna ;

Hill, Michael S. ;

Molloy, Kieran C. ;

Haque, Saif A. .

ADVANCED MATERIALS, 2011, 23 (24) :2739-2744

[7] Mesoscopic CH3NH3PbI3/TiO2 Heterojunction Solar Cells [J].

Etgar, Lioz ;

Gao, Peng ;

Xue, Zhaosheng ;

Peng, Qin ;

Chandiran, Aravind Kumar ;

Liu, Bin ;

Nazeeruddin, Md. K. ;

Graetzel, Michael .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (42) :17396-17399

[8] Solar cell efficiency tables (version 40) [J].

Green, Martin A. ;

Emery, Keith ;

Hishikawa, Yoshihiro ;

Warta, Wilhelm ;

Dunlop, Ewan D. .

PROGRESS IN PHOTOVOLTAICS, 2012, 20 (05) :606-614

[9] Hybrid solar cells with prescribed nanoscale morphologies based on hyperbranched semiconductor nanocrystals [J].

Gur, Ilan ;

Fromer, Neil A. ;

Chen, Chih-Ping ;

Kanaras, Antonios G. ;

Alivisatos, A. Paul .

NANO LETTERS, 2007, 7 (02) :409-414

[10] Dye-Sensitized Solar Cells [J].

Hagfeldt, Anders ;

Boschloo, Gerrit ;

Sun, Licheng ;

Kloo, Lars ;

Pettersson, Henrik .

CHEMICAL REVIEWS, 2010, 110 (11) :6595-6663

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