Hydrogen-absorbing alloys

被引：78

作者：

Akiba, E ^{[1
]}

机构：

[1] Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 3058565, Japan

来源：

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE | 1999年 / 4卷 / 03期

关键词：

D O I：

10.1016/S1359-0286(99)00026-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Improvement of hydrogen capacity in hydrogen-absorbing alloys has been achieved in recent years. Mg-based alloys which were synthesized by ball milling showed lower dehydrogenation temperatures than intermetallic Mg-based alloys. This technique is also effective for preparing a novel Mg-based amorphous alloy, MgNi, and its hydride. Besides conventional intermetallic compounds such as LaNi5, solid solution alloy, 'Laves phase related BCC solid solution' with body-centered-cubic structure showed a hydrogen capacity of 2.2 mass% at room temperature. Alanate, which is not an interstitial hydride, was found to react with gaseous hydrogen reversibly with a catalyst, and its hydrogen capacity was more than 3 mass%. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：267 / 272

页数：6

共 47 条

[31] The relation between the discharge capacity and cycling number of mechanically alloyed MgxNi100-x amorphous electrode alloys
Sun, DL
Lei, YQ
Liu, WH
Jiang, JJ
Wu, J
Wang, QD
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 231 (1-2) : 621 - 624
[32] Ball-milling of Mg2Ni under hydrogen
Tessier, P
Enoki, H
Bououdina, M
Akiba, E
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 268 (1-2) : 285 - 289
[33] Influence of oxygen on hydrogen storage and electrode properties for micro-designed V-based battery alloys
Tsukahara, M
Takahashi, K
Isomura, A
Sakai, T
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 265 (1-2) : 257 - 263
[34] METAL HYDRIDE ELECTRODES BASED ON SOLID-SOLUTION TYPE ALLOY TIV3NIX (0-LESS-THAN-OR-EQUAL-TO-X-LESS-THAN-OR-EQUAL-TO-0.75)
TSUKAHARA, M
TAKAHASHI, K
MISHIMA, T
SAKAI, T
MIYAMURA, H
KURIYAMA, N
UEHARA, I
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 226 (1-2) : 203 - 207
[35] Heat-treatment effects of V-based solid solution alloy with TiNi-based network structure on hydrogen storage and electrode properties
Tsukahara, M
Takahashi, K
Mishima, T
Isomura, A
Sakai, T
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 243 (1-2) : 133 - 138
[36] V-based solid solution alloys with Laves phase network: Hydrogen absorption properties and microstructure
Tsukahara, M
Takahashi, K
Mishima, T
Isomura, A
Sakai, T
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 236 (1-2) : 151 - 155
[37] PHASE-STRUCTURE OF V-BASED SOLID-SOLUTIONS CONTAINING TI AND NI AND THEIR HYDROGEN ABSORPTION-DESORPTION PROPERTIES
TSUKAHARA, M
TAKAHASHI, K
MISHIMA, T
SAKAI, T
MIYAMURA, H
KURIYAMA, N
UEHARA, I
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 224 (01) : 162 - 167
[38] Hydrogenation properties of Mg1-xM1xCu2 (M1 = La and Nd) with larger interstitial sites than MgCu2
Tsushio, Y
Tessier, P
Enoki, H
Akiba, E
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 280 (1-2) : 262 - 264
[39] Hydrogenation properties of Mg-based Laves phase alloys
Tsushio, Y
Akiba, E
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 269 (1-2) : 219 - 223
[40] Hydrogen desorption properties of the quaternary alloy system Mg2-xM1xNi1-yM2y
Tsushio, Y
Akiba, E
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 267 (1-2) : 246 - 251

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