(NBun4+)3[Re6S8Cl6]3-•:: synthesis and luminescence of the paramagnetic, open shell member of a hexanuclear chalcohalide cluster redox system

被引:80
作者
Guilbaud, C
Deluzet, A
Domercq, B
Molinié, P
Coulon, C
Boubekeur, K
Batail, P
机构
[1] Univ Nantes, Inst Mat Jean Rouxel, CNRS, UMR 6502, F-44322 Nantes, France
[2] CNRS, Ctr Rech Paul Pascal, F-33600 Pessac, France
关键词
D O I
10.1039/a904669k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The chemical and electrochemical synthesis, X-ray crystal structure, magnetic characterization, absorption and luminescence spectra of (NBu4n)(3)[Re6S8Cl6], the 23-electron cluster core member of the reversible redox couple [Re6S8Cl6](4-)-[Re6S8Cl6](3-.) is reported.
引用
收藏
页码:1867 / 1868
页数:2
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