Synthesis and solubility in water of Cs3Re6S7Cl7, the missing octahedral thiochloride rhenium(III) cluster salt

被引：9

作者：

Guilbaud, CB ^{[1
]}

Gabriel, JCP ^{[1
]}

Boubekeur, K ^{[1
]}

Batail, P ^{[1
]}

机构：

[1] Univ Nantes, Inst Mat Nantes, CNRS, UMR 6502, F-44322 Nantes 3, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1998年 / 1卷 / 12期

关键词：

octahedral chalcohalide rhenium cluster; water soluble; molecular mineral salt; trianion;

D O I：

10.1016/S1251-8069(99)80043-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the isostructural and isoelectronic series of molecular anions [Re-6(Y4+nX4-n)X-6](n-) (X = halogen, Y = chalcogen, n = 0-4), (Cs+)(3)[Re6S7Cl73-], the first n = 3 mineral salt has been obtained in quantitative amounts by high temperature solid state synthesis. It is found to be soluble in water where a metathesis of the alkaline cation affords (n-Bu4N)(3)Re6S7Cl7 in high yields. With this last compound, and for the first time in a Re-X-Y system, the completed series (n = 0-4) of molecular precursors is now available for solution chemistry. (C) Academie des sciences/Elsevier, Paris.

引用

页码：765 / 770

页数：6

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