Novel luminescent Au(I) pyrimidinethiolate dimer having an unusual π-stacking structure

被引：62

作者：

Hao, LJ

Lachicotte, RJ

Gysling, HJ

Eisenberg, R

机构：

[1] Univ Rochester, Sci & Technol Ctr Photoinduced Charge Transfer, Rochester, NY 14627 USA

[2] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

[3] Eastman Kodak Co, Imaging Mat Div, Rochester, NY 14650 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 21期

关键词：

D O I：

10.1021/ic990662t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new Au(I) dimethylpyrrimidinethiolate complexes have been synthesized. The dimer [Au(4,6-Me(2)pym-2-S)](2) possesses a solid state structure in which pi-stacking dominates over intermolecular Au ... Au bonding. In solution, the dimer gives evidence of facile dissociation while exhibiting concentration dependent luminescence.

引用

收藏

页码：4616 / +

页数：3

相关论文

共 29 条

[1]

[Anonymous], NMR SPECTROSCOPY

[2] SYNTHESES, STRUCTURES, AND SPECTROSCOPIC PROPERTIES OF GOLD(I) COMPLEXES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (TPA) - CORRELATION OF THE SUPRAMOLECULAR AU...AU INTERACTION AND PHOTOLUMINESCENCE FOR THE SPECIES (TPA)AUCL AND [(TPA-HCL)AUCL] [J].

ASSEFA, Z ;

MCBURNETT, BG ;

STAPLES, RJ ;

FACKLER, JP ;

ASSMANN, B ;

ANGERMAIER, K ;

SCHMIDBAUR, H .

INORGANIC CHEMISTRY, 1995, 34 (01) :75-83

[3] X-ray crystallographic and extended X-ray absorption fine structure studies of gold(I) complexes containing weak intermolecular interactions [J].

Bishop, P ;

Marsh, P ;

Brisdon, AK ;

Brisdon, BJ ;

Mahon, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (04) :675-682

[4] A two-co-ordinated gold(I) loop [Au(dpdo)]ClO4 [dpdo = 1,8-bis(diphenylphosphino)-3,6-dioxaoctane] as a luminescence light switch for substrate binding reactions [J].

Chan, WH ;

Mak, TCW ;

Che, CM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (14) :2275-2276

[5]

CRABTREE RH, 1994, ORGANOMETALLIC CHEM, pCH4

[6]

DEATON JC, 1991, Patent No. 5049485

[7] LUMINESCENCE STUDIES OF GOLD(I) THIOLATE COMPLEXES [J].

FORWARD, JM ;

BOHMANN, D ;

FACKLER, JP ;

STAPLES, RJ .

INORGANIC CHEMISTRY, 1995, 34 (25) :6330-6336

[8]

FORWARD JM, 1998, Z OPTOELECTRONIC PRO

[9] STRUCTURE OF AU2[S2CN(C2H5)2]2, BIS(DIETHYLDITHIOCARBAMATO)DIGOLD(I) [J].

HEINRICH, DD ;

WANG, JC ;

FACKLER, JP .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :1444-1447

[10] Spectroscopic and electronic properties of 1-azaallylmetal(I) (M = Cu or Au) complexes;: molecular structure of [{Au[μ-N(R)-C(Ph)CR2]}2] (R = SiMe3) [J].

Hitchcock, PB ;

Lappert, MF ;

Layh, M ;

Klein, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (09) :1455-1459