X-ray crystal structure of [VO(DPA)(H2O)2]•2H2O (DPA = dipicolinate dianion)

被引：21

作者：

Chatterjee, M

Ghosh, S ^{[1
]}

Nandi, AK

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Calcutta 700032, W Bengal, India

[2] Cent Glass & Ceram Res Inst, Calcutta 700032, W Bengal, India

来源：

TRANSITION METAL CHEMISTRY | 1999年 / 24卷 / 02期

关键词：

D O I：

10.1023/A:1006981321346

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray crystal structure of the trans-diaqua complex [VO(DPA)(H2O2)]. 2H(2)O (I) (DPA = dipicolinate dianion) has been determined. Comparison with the known structure of [VO(DPA)(o-phen)]. 3H(2)O (2), obtained from (1) by displacement of the two coordinated aqua molecules, shows that the coordination sphere around vanadium is reorganised during this reaction.

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页码：183 / 185

页数：3

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