Experimental determination of the oxygen solubility in benzene

被引:7
作者
Fischer, K
Noll, O
Gmehling, J
机构
[1] Carl Von Ossietzky Univ Oldenburg, FB Tech Chem 9, D-26111 Oldenburg, Germany
[2] Univ Oldenburg Inst, Lab Thermophys Properties LTP GmbH, Oldenburg, Germany
关键词
D O I
10.1021/je010163i
中图分类号
O414.1 [热力学];
学科分类号
摘要
Oxygen solubility in benzene was measured at pressures up to 0.4 MPa in the temperature range between 302.85 K and 332.63 K using a static synthetic method. The P,x data were correlated with the Soave-Redlich-Kwong equation of state and the Huron-Vidal mixing rule combined with the UNIQUAC model. From this correlation the Henry coefficients were derived and compared to data from literature. The experimental results were used together with literature data for fitting the interaction parameters between oxygen and the aromatic CH group of the predictive Soave-Redlich-Kwong (PSRK) model.
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页码:1504 / 1505
页数:2
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