Rational synthesis of platinabenzenes

被引：64

作者：

Landorf, CW ^{[1
]}

Jacob, V ^{[1
]}

Weakley, TJR ^{[1
]}

Haley, MM ^{[1
]}

机构：

[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 06期

关键词：

D O I：

10.1021/om034371a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of Cp*Pt(CO)I (8) with two nucleophilic (Z)-3-(2-lithiovinyl)cyclopropenes provides a rational synthesis of platinabenzenes 6 and 7. The intermediate a-vinyl complexes 9 and 10 are also isolated from the reaction mixtures and convert cleanly to the corresponding platinabenzenes in near-quantitative yield.

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收藏

页码：1174 / 1176

页数：3

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