Metallabenzenes

被引：351

作者：

Bleeke, JR ^{[1
]}

机构：

[1] Washington Univ, Dept Chem, St Louis, MO 63130 USA

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 05期

关键词：

D O I：

10.1021/cr990337n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A comprehensive study of the chemistry of transition-metal-containing metallabenzenes was carried out. Metallabenzenes represent a new class of aromatic compounds, in which metal d orbitals participate fully with carbon p orbitals in the formation of ring π-bonds. The results showed that the metallabenzenes are more prone to isomerization reactions than are conventional arenes.

引用

收藏

页码：1205 / 1227

页数：23

相关论文

共 70 条

[1] AROMATIC GALLIUM HETEROCYCLES - SYNTHESIS OF THE FIRST GALLATABENZENE [J].

ASHE, AJ ;

ALAHMAD, S ;

KAMPF, JW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (12) :1357-1359

[2] GROUP-5 HETEROBENZENES [J].

ASHE, AJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (04) :153-157

[3]

BADGER GM, 1969, AROMATIC CHARACIER A

[4]

Bergmann E. D., 1970, AROMATICITY PSEUDOAR

[5] TRIPLE-DECKER TO METALLABENZENE - A NEW-GENERATION OF SANDWICH COMPLEXES [J].

BERTLING, U ;

ENGLERT, U ;

SALZER, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (09) :1003-1004

[6] HDS MODEL SYSTEMS - COORDINATION, OPENING, AND HYDROGENATION OF BENZO[B]THIOPHENE AT IRIDIUM [J].

BIANCHINI, C ;

MELI, A ;

PERUZZINI, M ;

VIZZA, F ;

MONETI, S ;

HERRERA, V ;

SANCHEZDELGADO, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (10) :4370-4381

[7] OPENING, DESULFURIZATION, AND HYDROGENATION OF THIOPHENE AT IRIDIUM - AN EXPERIMENTAL-STUDY IN A HOMOGENEOUS PHASE [J].

BIANCHINI, C ;

MELI, A ;

PERUZZINI, M ;

VIZZA, F ;

FREDIANI, P ;

HERRERA, V ;

SANCHEZDELGADO, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (07) :2731-2742

[8] Synthesis, structure, spectroscopy, and reactivity of a metallathiabenzene [J].

Bleeke, JR ;

Hinkle, PV ;

Rath, NP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (03) :595-596

[9] Synthesis, spectroscopy, and reactivity of a metallapyrylium [J].

Bleeke, JR ;

Blanchard, JMB ;

Donnay, E .

ORGANOMETALLICS, 2001, 20 (02) :324-336

[10] Synthesis and reactivity of a metallapyrylium [J].

Bleeke, JR ;

Blanchard, JMB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (23) :5443-5444

← 1 2 3 4 5 6 7 →