Metallabenzenes

被引：351

作者：

Bleeke, JR ^{[1
]}

机构：

[1] Washington Univ, Dept Chem, St Louis, MO 63130 USA

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 05期

关键词：

D O I：

10.1021/cr990337n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A comprehensive study of the chemistry of transition-metal-containing metallabenzenes was carried out. Metallabenzenes represent a new class of aromatic compounds, in which metal d orbitals participate fully with carbon p orbitals in the formation of ring π-bonds. The results showed that the metallabenzenes are more prone to isomerization reactions than are conventional arenes.

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页码：1205 / 1227

页数：23

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