Reactivity of carbon dioxide toward zirconocene cations

被引：20

作者：

Hill, M ^{[1
]}

Wendt, OF ^{[1
]}

机构：

[1] Lund Univ, Dept Chem, S-22100 Lund, Sweden

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 23期

关键词：

D O I：

10.1021/om050741e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cationic methyl- and phenylzirconocene species readily undergo insertion of CO2 into the zirconium-carbon bond, giving the corresponding dimeric carboxylato complexes 12 and 13 in quantitative yield. 12 was structurally characterized, displaying a bridging acetate ligand.

引用

页码：5772 / 5775

页数：4

共 54 条

[51] INSERTION REACTIONS OF "DICYCLOPENTADIENYLDIMETHYLZIRCONIUM AND RELATED CYCLOPENTADIENYL COMPOUNDS WITH SULFUR-DIOXIDE AND NITRIC-OXIDE [J].