Axial chirality control of tropos BIPHEP-Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation

被引：29

作者：

Aikawa, Kohsuke ^{[1
]}

Takabayashi, Yuki ^{[1
]}

Kawauchi, Susumu ^{[2
]}

Mikami, Koichi ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Appl Chem, Tokyo 1528552, Japan

[2] Tokyo Inst Technol, Dept Organ & Polymer Mat, Tokyo 1528552, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 41期

关键词：

D O I：

10.1039/b809683j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Diastereopure tropos Rh complexes bearing not only BIPHEP but also chiral dienes can be employed as highly enantioselective hydrogenation catalysts for an olefinic substrate.

引用

页码：5095 / 5097

页数：3

共 41 条

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