Carboxamido nitrogens are good donors for Fe(III): Syntheses, structures, and properties of two low-spin nonmacrocyclic iron(III) complexes with tetracarboxamido-N coordination

被引：66

作者：

Marlin, DS

Olmstead, MM

Mascharak, PK ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 13期

关键词：

D O I：

10.1021/ic981461c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two nonmacrocyclic ligands with pyridine and carboxamide nitrogens as donors readily form his complexes of the type [(FeL2)-L-III](+) in which the Fe(III) centers exhibit preference for coordination to carboxamido nitrogens over pyridine nitrogens. These Fe(III) complexes with deprotonated carboxamido nitrogens are very stable in water.

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页码：3258 / +

页数：4

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