Honeycomb structures obtained with breath figures self-assembly allow water/oil separation

被引:45
作者
Bormashenko, Edward [1 ]
Balter, Sagi [2 ,3 ]
Bormashenko, Yelena [1 ]
Aurbach, Doron [3 ]
机构
[1] Ariel Univ, Ctr Samaria, Fac Phys, IL-40700 Ariel, Israel
[2] Ariel Univ, Ctr Samaria, Dept Chem & Biotechnol Engn, IL-40700 Ariel, Israel
[3] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
关键词
Breath-figures self-assembly; Hydrophobic surfaces; Oleophilic surfaces; Cassie wetting; Wenzel wetting; Rose petal effect; Water/oil separation; EVAPORATED POLYMER-SOLUTIONS; PATTERNED POROUS FILM; SURFACES; TEMPERATURE; OIL;
D O I
10.1016/j.colsurfa.2012.09.022
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
We report the development of a method of the breath figures self-assembly, allowing manufacturing of micro-scaled porous hydrophobic/oleophilic polymer surfaces. The stainless steel gauzes were used as carrying frameworks for polymer honeycomb reliefs resulting from the breath figures self-assembly. Two very different kinds of polymer reliefs arose from non-woven large aperture and micro-scaled woven gauzes. Both of them are hydrophobic and oleophilic, permeable for oils and impermeable for water. The micro-scaled woven gauzes promoted formation of reliefs manifesting the "rose petal effect", i.e. high apparent contact angles accompanied with the high contact angle hysteresis. This kind of reliefs turned out to be extremely efficient for water/oil separation. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:394 / 398
页数:5
相关论文
共 46 条
[1]
The rose petal effect and the modes of superhydrophobicity [J].
Bhushan, Bharat ;
Nosonovsky, Michael .
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2010, 368 (1929) :4713-4728
[2]
Formation of honeycomb patterns in evaporated polymer solutions: Influence of the molecular weight [J].
Bormashenko, E ;
Pogreb, R ;
Stanevsky, O ;
Bormashenko, Y ;
Gendelman, O .
MATERIALS LETTERS, 2005, 59 (28) :3553-3557
[3]
Mesoscopic and submicroscopic patterning in thin polymer films: Impact of the solvent [J].
Bormashenko, E ;
Pogreb, R ;
Stanevsky, O ;
Bormashenko, Y ;
Tamir, S ;
Cohen, R ;
Nunberg, M ;
Gaisin, VZ ;
Gorelik, M ;
Gendelman, OV .
MATERIALS LETTERS, 2005, 59 (19-20) :2461-2464
[4]
Self-assembled honeycomb polycarbonate films deposited on polymer piezoelectric substrates and their applications [J].
Bormashenko, E ;
Pogreb, R ;
Stanevsky, O ;
Bormashenko, Y ;
Socol, Y ;
Gendelman, O .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2005, 16 (04) :299-304
[5]
Mesoscopic patterning in evaporated polymer solutions: Poly(ethylene glycol) and room-temperature-vulcanized polyorganosilanes/-siloxanes promote formation of honeycomb structures [J].
Bormashenko, Edward ;
Malkin, Alexander ;
Musin, Albina ;
Bormashenko, Yelena ;
Whyman, Gene ;
Litvak, Natalya ;
Barkay, Zahava ;
Machavariani, Vladimir .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2008, 209 (06) :567-576
[6]
Contact angle hysteresis on polymer substrates established with various experimental techniques, its interpretation, and quantitative characterization [J].
Bormashenko, Edward ;
Bormashenko, Yelena ;
Whyman, Gene ;
Pogreb, Roman ;
Musin, Albina ;
Jager, Rachel ;
Barkay, Zahava .
LANGMUIR, 2008, 24 (08) :4020-4025
[7]
Formation of films on water droplets floating on a polymer solution surface [J].
Bormashenko, Edward ;
Musin, Albina ;
Bormashenko, Yelena ;
Whyman, Gene ;
Pogreb, Roman ;
Gendelman, Oleg .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2007, 208 (07) :702-709
[8]
Wetting transitions on biomimetic surfaces [J].
Bormashenko, Edward .
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2010, 368 (1929) :4695-4711
[9]
Free-Standing, Thermostable, Micrometer-Scale Honeycomb Polymer Films and their Properties [J].
Bormashenko, Edward ;
Schechter, Alex ;
Stanevsky, Oleg ;
Stein, Tamir ;
Balter, Sagi ;
Musin, Albina ;
Bormashenko, Yelena ;
Pogreb, Roman ;
Barkay, Zahava ;
Aurbach, Doron .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2008, 293 (11) :872-877
[10]
"Petal Effect" on Surfaces Based on Lycopodium: High-Stick Surfaces Demonstrating High Apparent Contact Angles [J].
Bormashenko, Edward ;
Stein, Tamir ;
Pogreb, Roman ;
Aurbach, Doron .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (14) :5568-5572