Three-Dimensional Hierarchical Architectures Constructed by Graphene/MoS2 Nanoflake Arrays and Their Rapid Charging/Discharging Properties as Lithium-Ion Battery Anodes

被引:146
作者
Yu, Hailong [1 ]
Ma, Chao [2 ]
Ge, Binghui [2 ]
Chen, Yujin [1 ]
Xu, Zheng [1 ]
Zhu, Chunling [3 ]
Li, Chunyan [1 ]
Ouyang, Qiuyun [1 ]
Gao, Peng [3 ]
Li, Jianqi [2 ]
Sun, Chunwen [2 ]
Qi, Lihong [1 ]
Wang, Yumei [2 ]
Li, Fanghua [2 ]
机构
[1] Harbin Engn Univ, Coll Sci, Harbin 150001, Peoples R China
[2] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
[3] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China
基金
中国国家自然科学基金;
关键词
graphene; lithium-ion battery; molybdenum; MoS2 nanoflake arrays; nanostructures; three-dimensional architectures; ELECTROMAGNETIC ABSORPTION PROPERTIES; ELECTROCHEMICAL PERFORMANCES; MOS2; NANOPARTICLES; EXFOLIATED MOS2; RATE CAPABILITY; HIGH-CAPACITY; STORAGE; NANOCOMPOSITES; CARBON; CATALYSTS;
D O I
10.1002/chem.201300072
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Charged up: Three-dimensional architectures constructed from graphene/MoS2 nanoflake arrays have been successfully fabricated by a one-step hydrothermal method. MoS2 nanoflakes with thicknesses less than 13 nm grow vertically on both sides of graphene sheets (see figure), which allows the architectures to be more stable during charging and discharging. Even at a high current density of 8000 mA g-1, their discharge capacity is still up to 516 mA h g-1. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:5818 / 5823
页数:6
相关论文
共 42 条
[1]   High-performance lithium battery anodes using silicon nanowires [J].
Chan, Candace K. ;
Peng, Hailin ;
Liu, Gao ;
McIlwrath, Kevin ;
Zhang, Xiao Feng ;
Huggins, Robert A. ;
Cui, Yi .
NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35
[2]   Single-layer MoS2/graphene dispersed in amorphous carbon: towards high electrochemical performances in rechargeable lithium ion batteries [J].
Chang, Kun ;
Chen, Weixiang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (43) :17175-17184
[3]   L-Cysteine-Assisted Synthesis of Layered MoS2/Graphene Composites with Excellent Electrochemical Performances for Lithium Ion Batteries [J].
Chang, Kun ;
Chen, Weixiang .
ACS NANO, 2011, 5 (06) :4720-4728
[4]   Graphene-like MoS2/amorphous carbon composites with high capacity and excellent stability as anode materials for lithium ion batteries [J].
Chang, Kun ;
Chen, Weixiang ;
Ma, Lin ;
Li, Hui ;
Li, He ;
Huang, Feihe ;
Xu, Zhude ;
Zhang, Qingbo ;
Lee, Jim-Yang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (17) :6251-6257
[5]   In situ synthesis of MoS2/graphene nanosheet composites with extraordinarily high electrochemical performance for lithium ion batteries [J].
Chang, Kun ;
Chen, Weixiang .
CHEMICAL COMMUNICATIONS, 2011, 47 (14) :4252-4254
[6]   Graphene/porous cobalt nanocomposite and its noticeable electrochemical hydrogen storage ability at room temperature [J].
Chen, Yujin ;
Wang, Qingshan ;
Zhu, Chunling ;
Gao, Peng ;
Ouyang, Qiuyun ;
Wang, Tieshi ;
Ma, Yang ;
Sun, Chunwen .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (13) :5924-5927
[7]  
Chens Y-J, 2008, APPL PHYS LETT, V92, P223101
[8]   Facile synthesis of hierarchical MoS2 microspheres composed of few-layered nanosheets and their lithium storage properties [J].
Ding, Shujiang ;
Zhang, Dongyang ;
Chen, Jun Song ;
Lou, Xiong Wen .
NANOSCALE, 2012, 4 (01) :95-98
[9]   Superior stability and high capacity of restacked molybdenum disulfide as anode material for lithium ion batteries [J].
Du, Guodong ;
Guo, Zaiping ;
Wang, Shiquan ;
Zeng, Rong ;
Chen, Zhixin ;
Liu, Huakun .
CHEMICAL COMMUNICATIONS, 2010, 46 (07) :1106-1108
[10]   Photoluminescence from Chemically Exfoliated MoS2 [J].
Eda, Goki ;
Yamaguchi, Hisato ;
Voiry, Damien ;
Fujita, Takeshi ;
Chen, Mingwei ;
Chhowalla, Manish .
NANO LETTERS, 2011, 11 (12) :5111-5116