Enantioselective hydrolyses with Yarrowia lipolytica:: a versatile strain for esters, enol esters, epoxides, and lactones

被引：19

作者：

Fantin, G ^{[1
]}

Fogagnolo, M ^{[1
]}

Guerrini, A ^{[1
]}

Medici, A ^{[1
]}

Pedrini, P ^{[1
]}

Fontana, S ^{[1
]}

机构：

[1] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 19期

关键词：

D O I：

10.1016/S0957-4166(01)00463-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Racemic secondary esters 1-3, gamma -lactones 8 9, and styrene oxide 7 are kinetically resolved via hydrolysis with Yarrowia lipolytica YL2 strain. The enantioselective hydrolysis of prochiral enol esters 4 6 to the corresponding homochiral carbonyl compounds 13-15 is also described. Subsequent reduction of the ketone 13 and of the aldehyde 15 can be avoided using lyophilised cells. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2709 / 2713

页数：5

共 31 条

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