Bisphosphine based hetero-capsules for the encapsulation of transition metals

被引:40
作者
Koblenz, TS
Dekker, HL
de Koster, CG
van Leeuwen, PWNM
Reek, JNH
机构
[1] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1018 WV Amsterdam, Netherlands
[2] Univ Amsterdam, Swammerdam Inst Life Sci, NL-1018 WV Amsterdam, Netherlands
关键词
D O I
10.1039/b518274c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Just mixing of solutions of tetracationic diphosphine ligands and tetraanionic calix[ 4] arene building blocks leads to the formation of supramolecular heterocapsules that coordinate a palladium metal within the cavity of the assembly, giving rise to a new class of potential supramolecular transition metal catalysts.
引用
收藏
页码:1700 / 1702
页数:3
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