Steric activation of chelate catalysts: efficient polyketone catalysts based on four-membered palladium(II) diphosphine chelates

被引:91
作者
Dossett, SJ
Gillon, A
Orpen, AG
Fleming, JS
Pringle, PG
Wass, DF
Jones, MD
机构
[1] BP, Sunbury On Thames TW16 7LN, Middx, England
[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
关键词
D O I
10.1039/b010063n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Palladium(ii) complexes of ligands of the type Ar2PCH2-PAr2 and Ar2PN(Me)PAr2 (Ar = ortho-substituted phenyl group) are very efficient catalysts for copolymerisation of CO and C2H4.
引用
收藏
页码:699 / 700
页数:2
相关论文
共 19 条
  • [1] COORDINATION CHEMISTRY OF DIPHOSPHINOAMINE AND CYCLODIPHOSPHAZANE LIGANDS
    BALAKRISHNA, MS
    REDDY, VS
    KRISHNAMURTHY, SS
    NIXON, JF
    STLAURENT, JCTRB
    [J]. COORDINATION CHEMISTRY REVIEWS, 1994, 129 (1-2) : 1 - 90
  • [2] Mechanistic studies of Alkene/CO polymerization with palladium complexes promoted by B(C6F5)3
    Barlow, GK
    Boyle, JD
    Cooley, NA
    Ghaffar, T
    Wass, DF
    [J]. ORGANOMETALLICS, 2000, 19 (08) : 1470 - 1476
  • [3] The bite angle makes the difference: a practical ligand parameter for diphosphine ligands
    Dierkes, P
    van Leeuwen, PWNM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (10): : 1519 - 1529
  • [4] Palladium complexes of C2-, C3-, and C4-bridged bis(phospholyl) ligands:: Remarkably active catalysts for the copolymerization of ethylene and carbon monoxide
    Doherty, S
    Eastham, GR
    Tooze, RP
    Scanlan, TH
    Williams, D
    Elsegood, MRJ
    Clegg, W
    [J]. ORGANOMETALLICS, 1999, 18 (18) : 3558 - 3560
  • [5] DOSSET SJ, 1997, Patent No. 9737765
  • [6] DOSSETT SJ, 2000, Patent No. 0003803
  • [7] DOSSETT SJ, 2000, Patent No. 0006299
  • [8] Palladium-catalyzed alternating copolymerization of alkenes and carbon monoxide
    Drent, E
    Budzelaar, PHM
    [J]. CHEMICAL REVIEWS, 1996, 96 (02) : 663 - 681
  • [9] Drent E, 1996, RECL TRAV CHIM PAY B, V115, P263
  • [10] Drent E., 1984, Patent No. [0121965B1, 0121965]