Steric activation of chelate catalysts: efficient polyketone catalysts based on four-membered palladium(II) diphosphine chelates

被引:91
作者
Dossett, SJ
Gillon, A
Orpen, AG
Fleming, JS
Pringle, PG
Wass, DF
Jones, MD
机构
[1] BP, Sunbury On Thames TW16 7LN, Middx, England
[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
关键词
D O I
10.1039/b010063n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Palladium(ii) complexes of ligands of the type Ar2PCH2-PAr2 and Ar2PN(Me)PAr2 (Ar = ortho-substituted phenyl group) are very efficient catalysts for copolymerisation of CO and C2H4.
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页码:699 / 700
页数:2
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