Octalanthanide wheels supported by p-tert-butylsulfonylcalix[4]arene

被引：106

作者：

Kajiwara, T ^{[1
]}

Wu, HS

Ito, T

Iki, N

Miyano, S

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

[2] Tohoku Univ, Grad Sch Engn, Dept Biomol Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 14期

关键词：

calixarenes; cluster compounds; lanthanides; macrocycles; magnetic properties;

D O I：

10.1002/anie.200353449

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cluster-forming ligsnd, p-tert-butylsulfonylcalix[4]arene (H 4L), allows the formation of lanthanide wheels whose cluster cores contain eight lanthanide ions (GdIII, SmIII, Nd III or PrIII; shown in green in the picture) connected by L4- ions, which act as both a tetradentate and a bisbidentate μ3-ligand, and eight bridging acetate groups. The wheels form by a step-by-step" process via the mononuclear subunit {Ln(L)} -."

引用

页码：1832 / 1835

页数：4

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