Octalanthanide wheels supported by p-tert-butylsulfonylcalix[4]arene

被引：106

作者：

Kajiwara, T ^{[1
]}

Wu, HS

Ito, T

Iki, N

Miyano, S

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

[2] Tohoku Univ, Grad Sch Engn, Dept Biomol Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 14期

关键词：

calixarenes; cluster compounds; lanthanides; macrocycles; magnetic properties;

D O I：

10.1002/anie.200353449

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cluster-forming ligsnd, p-tert-butylsulfonylcalix[4]arene (H 4L), allows the formation of lanthanide wheels whose cluster cores contain eight lanthanide ions (GdIII, SmIII, Nd III or PrIII; shown in green in the picture) connected by L4- ions, which act as both a tetradentate and a bisbidentate μ3-ligand, and eight bridging acetate groups. The wheels form by a step-by-step" process via the mononuclear subunit {Ln(L)} -."

引用

页码：1832 / 1835

页数：4

共 39 条

[21] Sulfonylcalix[4]arene as a bis-tridentate facial ligand:: Syntheses and structures of dinuclear complexes, [M2(L)(H2O)2(dmf)4] (M = Co(II), Ni(II);: H4L = p-tert-butylsulfonylcalix[4]arene)
Kajiwara, T
Yokozawa, S
Ito, T
Iki, N
Morohashi, N
Miyano, S
[J]. CHEMISTRY LETTERS, 2001, (01) : 6 - 7
[22] Kajiwara T, 2002, ANGEW CHEM INT EDIT, V41, P2076, DOI 10.1002/1521-3773(20020617)41:12<2076::AID-ANIE2076>3.0.CO
[23] 2-2
[24] p-tert-Butylthiacalix[6]arene as a clustering ligand.: Syntheses and structures of CoII5, NiII4, and mixed-metal MIINiII4 (M = Mn, Co, and Cu) cluster complexes, and a novel metal-induced cluster core rearrangement
Kajiwara, T
Shinagawa, R
Ito, T
Kon, N
Iki, N
Miyano, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2003, 76 (12) : 2267 - 2275
[25] Synthesis, structure, and ferromagnetic behavior of decacopper(II) cluster complex supported by hexaanionic p-tert-butylthiacalix[6]arene
Kajiwara, T
Kon, N
Yokozawa, S
Ito, T
Iki, N
Miyano, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (38) : 11274 - 11275
[26] Kajiwara T., 2002, ANGEW CHEM, V114, P2180
[27] Larsen F.K., 2003, Angew. Chem, V115, P105, DOI DOI 10.1002/ANGE.200390002
[28] Synthesis and chracterization of heterometallic [Cr7M] wheels
Larsen, FK
McInnes, EJL
El Mkami, H
Overgaard, J
Piligkos, S
Rajaraman, G
Rentschler, E
Smith, AA
Smith, GM
Boote, V
Jennings, M
Timco, GA
Winpenny, REP
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (01) : 101 - 105
[29] [MO-154(NO)(14)O-420(OH)(28)(H2O)(70)]((25+5)-) - A WATER-SOLUBLE BIG WHEEL WITH MORE THAN 700 ATOMS AND A RELATIVE MOLECULAR-MASS OF ABOUT 24000
MULLER, A
KRICKEMEYER, E
MEYER, J
BOGGE, H
PETERS, F
PLASS, W
DIEMANN, E
DILLINGER, S
NONNENBRUCH, F
RANDERATH, M
MENKE, C
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (19): : 2122 - 2124
[30] Muller A., 1995, ANGEW CHEM, V107, P2293

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