Sulfonylcalix[4]arene as a bis-tridentate facial ligand:: Syntheses and structures of dinuclear complexes, [M2(L)(H2O)2(dmf)4] (M = Co(II), Ni(II);: H4L = p-tert-butylsulfonylcalix[4]arene)
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作者:
Kajiwara, T
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机构:Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
Kajiwara, T
Yokozawa, S
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机构:Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
Yokozawa, S
Ito, T
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Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, JapanTohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
Ito, T
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Iki, N
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机构:Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
Iki, N
Morohashi, N
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机构:Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
Morohashi, N
Miyano, S
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机构:Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
Miyano, S
机构:
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
[2] Tohoku Univ, Dept Biomol Engn, Grad Sch Engn, Sendai, Miyagi 9808579, Japan
Cobalt(II) and nickel(II) complexes with a tetraanionic ligand of p-tert-butylsulfonylcalix[4]arene were synthesized and their X-ray structures show that the calixarene acts as a bis-tridentate dinucleating ligand with the 1.2-alternate conformation.