Coordination of epithio groups of p-tert-butylthiacalix[4]arene in a Zn2+ complex studied by X-ray crystallography

被引：86

作者：

Iki, N

Morohashi, N

Kabuto, C

Miyano, S

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Biomol Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan

[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808579, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 03期

关键词：

D O I：

10.1246/cl.1999.219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single-crystal X-ray analysis has shown that p-tert-butylthiacalix[4]arene (H4L) binds to Zn2+ ion by bridging sulfur atoms in addition to phenolic oxygen atoms to form [Zn4L(H2L)(2)].

引用

页码：219 / 220

页数：2

共 7 条

[1]

DUBBERLEY SR, 1997, J CHEM SOC CHEM COMM, P1603

[2] Selective synthesis of three conformational isomers of tetrakis[(ethoxycarbonyl)methoxy]thiacalix[4]arene and their complexation properties towards alkali metal ions [J].

Iki, N ;

Narumi, F ;

Fujimoto, T ;

Morohashi, N ;

Miyano, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1998, (12) :2745-2750

[3] High complexation ability of thiacalixarene with transition metal ions. The effects of replacing methylene bridges of tetra(p-t-butyl)calix[4]arenetetrol by epithio groups [J].

Iki, N ;

Morohashi, N ;

Narumi, F ;

Miyano, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (07) :1597-1603

[4] A new water-soluble host molecule derived from thiacalixarene [J].

Iki, N ;

Fujimoto, T ;

Miyano, S .

CHEMISTRY LETTERS, 1998, (07) :625-626

[5] A new chiral stationary phase for gas chromatography by use of a chiral thiacalix[4]arene derivative [J].

Iki, N ;

Narumi, F ;

Suzuki, T ;

Sugawara, A ;

Miyano, S .

CHEMISTRY LETTERS, 1998, (10) :1065-1066

[6] Selective oxidation of thiacalix[4]arenes to the sulfinyl- and sulfonylcalix[4]arenes and their coordination ability to metal ions [J].

Iki, N ;

Kumagai, H ;

Morohashi, N ;

Ejima, K ;

Hasegawa, M ;

Miyanari, S ;

Miyano, S .

TETRAHEDRON LETTERS, 1998, 39 (41) :7559-7562

[7] Facile synthesis of p-tert-butylthiacalix[4]arene by the reaction of p-tert-butylphenol with elemental sulfur in the presence of a base [J].

Kumagai, H ;

Hasegawa, M ;

Miyanari, S ;

Sugawa, Y ;

Sato, Y ;

Hori, T ;

Ueda, S ;

Kamiyama, H ;

Miyano, S .

TETRAHEDRON LETTERS, 1997, 38 (22) :3971-3972

← 1 →