Polymorphism of 1,3,5-trinitrobenzene induced by a trisindane additive

被引：122

作者：

Thallapally, PK

Jetti, RKR

Katz, AK

Carrell, HL

Singh, K

Lahiri, K

Kotha, S

Boese, R

Desiraju, GR

机构：

[1] Univ Duisburg Essen, Inst Anorgan Chem, D-45177 Essen, Germany

[2] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

[3] Fox Chase Canc Ctr, Inst Canc Res, Philadelphia, PA 19111 USA

[4] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 09期

关键词：

additives; crystal growth; inhibition; polymorphism;

D O I：

10.1002/anie.200352253

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The most stable is not necessarily the most easy to obtain! Two new stable crystal forms of the 120 year old compound sym-trinitrobenzene are reported. These elusive forms have been obtained by the use of an additive, trisindane, that can act as a mimic in the crystallization experiment (see scheme).

引用

页码：1149 / 1155

页数：7

共 58 条

[31] Dipole-induced polymorphs of trans-2-hydroxycycloheptanecarboxylic acid with virtually the same unit cell [J].