Lithium secondary batteries using modified-imidazolium room-temperature ionic liquid

被引：312

作者：

Seki, Shiro

Kobayashi, Yo

Miyashiro, Hajime

Ohno, Yasutaka

Usami, Akira

Mita, Yuichi

Kihira, Nobuo

Watanabe, Masayoshi

Terada, Nobuyuki

机构：

[1] Cent Res Inst Elect Power Ind, Mat Sci Res Lab, Tokyo 2018511, Japan

[2] Elect Power Engn Syst Co Ltd, Tokyo 2018511, Japan

[3] Yokohama Natl Univ, Dept Chem & Biotechnol, Hodogaya Ku, Kanagawa 2408501, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2006年 / 110卷 / 21期

关键词：

D O I：

10.1021/jp0620872

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Highly reversible, safe lithium secondary batteries that use imidazolium-cation-based room-temperature ionic liquid as an electrolyte and lithium metal as an anode material were realized by the molecular design. To achieve higher reduction stability, an electron-donating substituent was introduced to promote charge delocalization in the imidazolium cation of room-temperature ionic liquids.

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页码：10228 / 10230

页数：3

相关论文

共 19 条

[1] Raman investigation of the ionic liquid N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide and its mixture with LiN(SO2CF3)2 [J].

Castriota, M ;

Caruso, T ;

Agostino, RG ;

Cazzanelli, E ;

Henderson, WA ;

Passerini, S .

JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (01) :92-96

[2] Analysis of recent measurements of the viscosity of glasses [J].

Fulcher, GS .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1925, 8 (06) :339-355

[3] The room temperature ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate: Electrochemical couples and physical properties [J].

Fuller, J ;

Carlin, RT ;

Osteryoung, RA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (11) :3881-3886

[4] Room temperature molten salts as lithium battery electrolyte [J].

Garcia, B ;

Lavallée, S ;

Perron, G ;

Michot, C ;

Armand, M .

ELECTROCHIMICA ACTA, 2004, 49 (26) :4583-4588

[5] Alkylated imidazolium salt electrolyte for lithium cells [J].

Hayashi, K ;

Nemoto, Y ;

Akuto, K ;

Sakurai, Y .

JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :689-692

[6] High lithium metal cycling efficiency in a room-temperature ionic liquid [J].

Howlett, PC ;

MacFarlane, DR ;

Hollenkamp, AF .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (05) :A97-A101

[7]

ISHIKAWA M, 2006, J POWER SOURCES

[8]

MATSUMOTO H, 2006, J POWER SOURCES

[9] Liquid and polymer gel electrolytes for lithium batteries composed of room-temperature molten salt doped by lithium salt [J].

Nakagawa, H ;

Izuchi, S ;

Kuwana, K ;

Nukuda, T ;

Aihara, Y .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (06) :A695-A700

[10] N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP 13-TFSI) -: novel electrolyte base for Li battery [J].

Sakaebe, H ;

Matsumoto, H .

ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (07) :594-598