Preparation and reactions of rhodium complexes of some alkenyloxy- and alkenylamino-benzylamines and related compounds: A comparison with catalytic reactions

被引：5

作者：

Campi, EM

Jackson, WR

McCubbin, QJ

Trnacek, AE

机构：

[1] Department of Chemistry, Monash University, Clayton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 539卷 / 1-2期

基金：

澳大利亚研究理事会;

关键词：

rhodium; stoichiometric complexes; catalysis; rearrangement; cyclisation; allylic cleavage;

D O I：

10.1016/S0022-328X(97)00037-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of several allyloxy- and allylamino-benzylamines and a benzamide with [Rh(CO)(2)Cl](2) give monodentate rhodium complexes which show no evidence of alkene coordination. Reaction of these and related compounds with HRh(CO)(PPh3)(3) give products arising from double bond isomerisation followed by cyclisation or liberation of propene. The results are compared with rhodium-catalysed reactions of these substrates with H-2/CO. (C) 1997 Published by Elsevier Science S.A.

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页码：147 / 153

页数：7

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