The synthesis of bis(oligophenyleneethynylenes): novel potential nonlinear optical materials

被引：8

作者：

Armitt, DJ ^{[1
]}

Crisp, GT ^{[1
]}

机构：

[1] Univ Adelaide, Sch Chem & Phys, Adelaide, SA 5005, Australia

来源：

TETRAHEDRON | 2006年 / 62卷 / 07期

基金：

澳大利亚研究理事会;

关键词：

nonlinear optics; Sonogashira coupling; alkynes;

D O I：

10.1016/j.tet.2005.11.015

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various functionalised phenyleneethynylene dimers 10 and trimers 12 were synthesised by palladium-catalyzed Sonogashira methodology. These dimers and trimers were coupled to 1,8-diido-10-methoxyanthracene to generate bis(oligophenyleneethynylenes) 17 and 18. Preliminary results towards the construction of both phenyleneethynylene and phenylenevinylene hybrid motifs are presented. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：1485 / 1493

页数：9

共 71 条

[31] Combinatorial synthesis of oligo(phenylene ethynylene)s
Hwang, JJ
Tour, JM
[J]. TETRAHEDRON, 2002, 58 (52) : 10387 - 10405
[32] Molecular structures of related compounds of mesogens studied by 1H NMR using a liquid crystal solvent:: Tolan and trans-azobenzene
Inoue, K
Takeuchi, H
Konaka, S
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (27) : 6711 - 6716
[33] Rapid solution and solid phase syntheses of oligo(1,4-phenylene ethynylene)s with thioester termini: Molecular scale wires with alligator clips. Derivation of iterative reaction efficiencies on a polymer support
Jones, L
Schumm, JS
Tour, JM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (05) : 1388 - 1410
[34] Control of conformational and interpolymer effects in conjugated polymers
Kim, J
Swager, TM
[J]. NATURE, 2001, 411 (6841) : 1030 - 1034
[35] Preparation, structure and properties of novel 1,3-dithiol-2-ylidene derivatives containing bis(ethynylpyridine) units
Kumagai, T
Tomura, M
Nishida, J
Yamashita, Y
[J]. TETRAHEDRON LETTERS, 2003, 44 (36) : 6845 - 6848
[36] Molecules with quinoid ground state: a new class of large molecular optical nonlinearities?
Lanata, M
Bertarelli, C
Gallazzi, MC
Bianco, A
Del Zoppo, M
Zerbi, G
[J]. SYNTHETIC METALS, 2003, 138 (1-2) : 357 - 362
[37] Sequential catalytic synthesis of rod-like conjugated poly-ynes
Lavastre, O
Ollivier, L
Dixneuf, PH
Sibandhit, S
[J]. TETRAHEDRON, 1996, 52 (15) : 5495 - 5504
[38] Steps to demarcate the effects of chromophore aggregation and planarization in poly(phenyleneethynylene)s. 1. Rotationally interrupted conjugation in the excited states of 1,4-bis(phenylethynyl)benzene
Levitus, M
Schmieder, K
Ricks, H
Shimizu, KD
Bunz, UHF
Garcia-Garibay, MA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (18) : 4259 - 4265
[39] Convenient synthesis of 1,8-diiodoanthracene and its coupling with thianthrene boronic acids
Lovell, JM
Joule, JA
[J]. SYNTHETIC COMMUNICATIONS, 1997, 27 (07) : 1209 - 1215
[40] Marder S. R., 1991, ACS SYM SER, V455, DOI 10.1021/bk-1991-0455

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