The synthesis of bis(oligophenyleneethynylenes): novel potential nonlinear optical materials

被引:8
作者
Armitt, DJ [1 ]
Crisp, GT [1 ]
机构
[1] Univ Adelaide, Sch Chem & Phys, Adelaide, SA 5005, Australia
基金
澳大利亚研究理事会;
关键词
nonlinear optics; Sonogashira coupling; alkynes;
D O I
10.1016/j.tet.2005.11.015
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Various functionalised phenyleneethynylene dimers 10 and trimers 12 were synthesised by palladium-catalyzed Sonogashira methodology. These dimers and trimers were coupled to 1,8-diido-10-methoxyanthracene to generate bis(oligophenyleneethynylenes) 17 and 18. Preliminary results towards the construction of both phenyleneethynylene and phenylenevinylene hybrid motifs are presented. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1485 / 1493
页数:9
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