Investigation of electronic trap states in organic photovoltaic materials by current-based deep level transient spectroscopy

被引:29
作者
Neugebauer, Stefan [1 ]
Rauh, Julia [1 ]
Deibel, Carsten [1 ]
Dyakonov, Vladimir [1 ,2 ]
机构
[1] Univ Wurzburg, Fac Phys & Astron, D-97074 Wurzburg, Germany
[2] Bavarian Ctr Appl Energy Res ZAE Bayern, D-97074 Wurzburg, Germany
关键词
LIGHT-EMITTING-DIODES; MEH-PPV; SEMICONDUCTORS; REGULARIZATION; PHTHALOCYANINE; TRANSPORT; MODEL;
D O I
10.1063/1.4731637
中图分类号
O59 [应用物理学];
学科分类号
摘要
Current-based deep level transient spectroscopy was used to study trap states in poly(3-hexylthiophene-2,5-diyl) (P3HT), [6,6]-phenyl-C61 butyric acid methyl ester (PCBM), and P3HT: PCBM blend. The obtained spectra showed traps of 87 meV activation energy in pure P3HT and 21 meV for PCBM. The blend shows a complex emission rate spectrum consisting of several different emission rate bands in the range of 0.1-30 s(-1), yielding activation energies between about 30 meV and 160 meV. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4731637]
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页数:4
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