Carbon nanotubes with Pt-Ru catalyst for methanol fuel cell

被引:78
作者
Frackowiak, E
Lota, G
Cacciaguerra, T
Béguin, F
机构
[1] Poznan Univ Tech, Inst Chem & Tech Electrochem, PL-60965 Poznan, Poland
[2] Univ Orleans, CNRS, CRMD, F-45071 Orleans 02, France
关键词
carbon nanotubes; methanol oxidation; platinum/ruthenium;
D O I
10.1016/j.elecom.2005.10.015
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Multiwalled carbon nanotubes (NTs) have been used as an attractive support of catalytic metallic particles for methanol electrooxidation in acidic medium. Pt-Ru (50:50) nanoparticles were deposited on the different type of nanotubular materials to select the best support and to estimate the efficiency of CH3OH oxidation. Pt-Ru supported on NTs graphitized at 2500 degrees C supply the optimal voltage/current characteristics with a maximum current load of 2.7 A/g. Mesoporous network of nanotubes combined with their excellent conducting properties allows a quick transport and easy accessibility of the reagent molecules to the catalytic sites of electrode interface giving a good performance of methanol anode. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:129 / 132
页数:4
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