Twelve One-Electron Ligands Coordinating One Metal Center: Structure and Bonding of [Mo(ZnCH3)9(ZnCp*)3]

被引：69

作者：

Cadenbach, Thomas ^{[2
]}

Bollermann, Timo ^{[2
]}

Gemel, Christian ^{[2
]}

Fernandez, Israel ^{[3
]}

von Hopffgarten, Moritz ^{[1
]}

Frenking, Gernot ^{[1
]}

Fischer, Roland A. ^{[2
]}

机构：

[1] Univ Marburg, Dept Chem, D-35032 Marburg, Germany

[2] Ruhr Univ Bochum, Fac Chem & Biochem, D-44870 Bochum, Germany

[3] Univ Complutense Madrid, Dpto Quim Organ, Fac Quim, E-28040 Madrid, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 47期

关键词：

cluster compounds; coordination chemistry; gallium; molybdenum; zinc;

D O I：

10.1002/anie.200802811

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Surrounded by zinc: The reaction of [Mo-(GaCp*)6] and Zn(CH3)2 zinc yields the exceptionally high-coordinate title compound (see picture; Mo red, Zn green, C gray). Quantum chemical analysis reveals a unique bonding situation best described as a perfectly sd5 hybridized molybdenum atom with 12 valence electrons engagedin Mo-Zn bonding. Another six electrons are delocalized over the Zn cage, evoking only weak Zn-Zn interactions. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9150 / 9154

页数：5

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