Actinide-mediated cyclization of 1,2,4,5-tetracyanobenzene: Synthesis and characterization of self-assembled trinuclear thorium and uranium macrocycles

被引：39

作者：

Kiplinger, JL ^{[1
]}

Pool, JA ^{[1
]}

Schelter, EJ ^{[1
]}

Thompson, JD ^{[1
]}

Scott, BL ^{[1
]}

Morris, DE ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 13期

关键词：

metallomacrocycles; self-assembly; tetracyanobenzene; thorium; uranium;

D O I：

10.1002/anie.200504306

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Heavy metal triangles: A class of actinide metallomacrocycles has been prepared in which three (C5Me 5)2An (An = Th, U) fragments are coordinated by three 5,6-dicyano-1-methyl-3-(N-methylamino)-isoindolyl bridging ligands (N blue). The tetravalent actinide centers form a triangular array in the products obtained through an unprecedented actinide-mediated cyclization of 1,2,4,5- tetracyanobenzene and subsequent self-assembly. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：2036 / 2041

页数：6

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