A Linear Actuation of Polymeric Nanofibrous Bundle for Artificial Muscles

被引:78
作者
Gu, Bon Kang [1 ]
Ismail, Yahya A. [1 ]
Spinks, Geoffrey A. [2 ]
Kim, Sun I. [1 ]
So, Insuk [3 ]
Kim, Seon Jeong [1 ]
机构
[1] Hanyang Univ, Creat Res Ctr Bioartificial Muscle, Dept Biomed Engn, Seoul 133791, South Korea
[2] Univ Wollongong, Intelligent Polymer Res Inst, Wollongong, NSW, Australia
[3] Seoul Natl Univ, Dept Physiol, Seoul, South Korea
关键词
POLYANILINE ACTUATORS; FIBERS; CARBON; PANI(AMPS);
D O I
10.1021/cm802377d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Artificial muscle fiber mimicking myofibril is fabricated using electrospun nanofibers of high strength polyurethane followed by controlled in situ chemical polymerization with aniline. The resulting polyurethane(PU)/polyaniline(PANi) hybrid nanofibrous bundle consisting individual nanofibers of about 900 nm diameter responds to an electrical stimuli producing a linear actuation strain as high as 1.65% at an applied stress of 1.03 MPa in 1 M methane sulfonic acid (MSA), the highest strain produced in the nanofibers templated PANi. The hybrid nanofibrous bundle shows an electrical conductivity of about 0.5 S/cm and the electroactivity is imparted by PANi. The biomimetic artificial nanofibrous bundle shows work per cycle (W.C.) efficiency of above 75% for the electrochemical actuation even beyond 100 cycles. The PU/PANi hybrid nanofibrous bundle could be stably actuated without significant creep up to an applied load of 11 mN (2.263 Mpa) beyond which significant creep behavior appears.
引用
收藏
页码:511 / 515
页数:5
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