Copper sulfides by chemical spray pyrolysis process

被引：31

作者：

Krunks, M

Mellikov, E

Bijakina, O

机构：

来源：

PHYSICA SCRIPTA | 1997年 / T69卷

关键词：

D O I：

10.1088/0031-8949/1997/T69/037

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The chemistry of formation of copper sulfide and copper indium disulfide films by the chemical spray pyrolysis process has been investigated. It was established that the formation of copper sulfide films by the spray process of water solutions of CuCl2 and SC(NH2)(2) passes through the stage of formation of intermediate complex compound Cu(SCN2H4)Cl . H2O in the initial solution. Thermal behaviour studies in air exhibit rearrangement of the complex at temperatures higher than 210 degrees C with formation of copper sulfide. Copper oxide is the decomposition product at temperatures higher than 700 degrees C in air. CuInS2 is formed by the reaction between copper and indium sulfides.

引用

页码：189 / 192

页数：4

共 15 条

[1] ADURODIJA FO, 1994, 12 EUR PHOT SOL EN C, V1, P6211
[2] PROPERTIES OF CUINS2 THIN-FILMS PREPARED BY SPRAY PYROLYSIS
BIHRI, H
MESSAOUDI, C
SAYAH, D
BOYER, A
MZERD, A
ABDLEFDIL, M
[J]. PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1992, 129 (01): : 193 - 200
[3] SOLUTION CHEMISTRY IN THE FORMATION OF SINGLE-PHASE CULNSE2 BY SPRAY PYROLYSIS
BROWN, BJ
HABA, B
BATES, CW
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (06) : 1559 - 1561
[4] SIMILARITIES IN THE CHEMICAL MECHANISMS OF CUINSE2 AND CDS THIN-FILM FORMATION BY CHEMICAL SPRAY PYROLYSIS
BROWN, BJ
BATES, CW
[J]. THIN SOLID FILMS, 1990, 188 (02) : 301 - 305
[5] HERNANDEZROJAS JL, 1994, 12 EUR PHOT SOL EN C, V1, P613
[6] KRUNKS M, 1996, IN PRESS ACTA CHEM A, V50
[7] KRUNKS M, 1995, P TALLINN TU, V741, P103
[8] Krunks M, 1996, P EST ACAD SCI, V2, P98
[9] OPTICAL AND SURFACE-PROPERTIES OF SPRAY-PYROLYZED CDS THIN-FILMS
MATHEW, S
MUKERJEE, PS
VIJAYAKUMAR, KP
[J]. THIN SOLID FILMS, 1995, 254 (1-2) : 278 - 284
[10] SPRAY PYROLYSIS OF CUINSE2
MOONEY, JB
LAMOREAUX, RH
[J]. SOLAR CELLS, 1986, 16 (1-4): : 211 - 220

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