Self-repairing mechanism of plastics

被引：30

作者：

Takeda, Kunihiko ^{[1
]}

Tanahashi, Mitsuru ^{[1
]}

Unno, Haruo ^{[2
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Mat Sci & Engn, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648603, Japan

[2] Shibaura Inst Technol, Grad Sch Engn, Dept Mat Sci & Engn, Minato Ku, 3-9-14 Shibaura, Tokyo 1088548, Japan

来源：

SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS | 2003年 / 4卷 / 05期

关键词：

Self-repairing; Plastics; Metabolism; Evolution; Man-made materials;

D O I：

10.1016/j.stam.2003.10.004

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The protection mechanism of a living body and man-made materials can be classified into two categories. One is a passive protection by which the body and materials are guarded by simple chemicals such as light absorbents, and the other is an active protection that repairs with metabolic reactions the internal injury suffered by many kinds of deterioration factors from the outside. Polyphenylene-ether was selected as a man-made material in which the metabolic reaction can be achieved in the atmosphere (21% of oxygen) and at room temperature (20-40 degrees C). The polymer introduces oxygen as an energy source, transports it with copper-complex and repairs the scission point of the chain. Such active protections were attempted for several polymers and some advantages and problems were elucidated. In this paper, the mechanisms of active protections in some plastics are reviewed and are also compared with protection systems of a living body, which provide us with very useful information on the development of advanced materials. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：435 / 444

页数：10

共 68 条

[51] Molecular rearrangement by thermal degradation of poly(oxy-2,6-dimethyl-1,4-phenylene) [J].

Takayama, S ;

Arai, T ;

Kinoshita, M ;

Takeda, K .

KOBUNSHI RONBUNSHU, 1996, 53 (05) :284-293

[52]

Takeda K, 1997, J APPL POLYM SCI, V64, P1175, DOI 10.1002/(SICI)1097-4628(19970509)64:6<1175::AID-APP18>3.0.CO

[53]

2-V

[54]

Takeda K, 1997, J APPL POLYM SCI, V66, P2279, DOI 10.1002/(SICI)1097-4628(19971219)66:12<2279::AID-APP9>3.0.CO

[55]

2-D

[56]

TAKEDA K, 2002, J JAPAN SOC APPL SCI, V16, P19

[57]

TAKEDA K, 2003, 1 WORKSH SURV FUT MA

[58]

TSUGE S, 1989, FUNDAMENTAL DATA POL, P45

[59]

UNNO H, 2001, P 10 POL MAT FOR, P241

[60] POLYMERIZATION BY OXIDATION COUPLING .1. A STUDY OF OXIDATION OF 2,6-DIPHENYLPHENOL TO POLY(2,6-DIPHENYL-1,4-PHENYLENE ETHER) [J].

WHITE, DM ;

KLOPFER, HJ .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1970, 8 (06) :1427-&

← 1 2 3 4 5 6 7 →