A new isoreticular class of metal-organic-frameworks with the MIL-88 topology

被引:473
作者
Surblé, S
Serre, C
Mellot-Draznieks, C
Millange, F
Férey, G
机构
[1] Univ Versailles St Quentin en Yvelines, UMR 8637, CNRS, Inst Lavoisier, F-78035 Versailles, France
[2] UCL Royal Inst Great Britain, London W1S 4BS, England
关键词
D O I
10.1039/b512169h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report here a new family of isoreticular MOFs, comprising three larger analogues of the nanoporous metallocarboxylate MIL-88; these solids were synthesized using a controlled SBU approach and the three crystal structures were solved using an original simulation-assisted structure determination method in direct space.
引用
收藏
页码:284 / 286
页数:3
相关论文
共 22 条
[1]  
[Anonymous], 1997, SHELXL97
[2]   The application of structure envelopes in structure determination from powder diffraction data [J].
Brenner, S ;
McCusker, LB ;
Baerlocher, C .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2002, 35 :243-252
[3]   BOND-VALENCE PARAMETERS FOR SOLIDS [J].
BRESE, NE ;
OKEEFFE, M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197
[4]   Recent advances in metal phosphonate chemistry [J].
Clearfield, A .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1996, 1 (02) :268-278
[5]   Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].
Eddaoudi, M ;
Moler, DB ;
Li, HL ;
Chen, BL ;
Reineke, TM ;
O'Keeffe, M ;
Yaghi, OM .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330
[6]   New materials in hydrothermal synthesis [J].
Feng, SH ;
Xu, RR .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (03) :239-247
[7]   A hybrid solid with giant pores prepared by a combination of targeted chemistry, simulation, and powder diffraction [J].
Férey, G ;
Serre, C ;
Mellot-Draznieks, C ;
Millange, F ;
Surblé, S ;
Dutour, J ;
Margiolaki, I .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (46) :6296-6301
[8]   A chromium terephthalate-based solid with unusually large pore volumes and surface area [J].
Férey, G ;
Mellot-Draznieks, C ;
Serre, C ;
Millange, F ;
Dutour, J ;
Surblé, S ;
Margiolaki, I .
SCIENCE, 2005, 309 (5743) :2040-2042
[9]   Microporous solids:: From organically templated inorganic skeletons to hybrid frameworks ... ecumenism in chemistry [J].
Férey, G .
CHEMISTRY OF MATERIALS, 2001, 13 (10) :3084-3098
[10]   Crystallized frameworks with giant pores:: Are there limits to the possible? [J].
Férey, G ;
Mellot-Draznieks, C ;
Serre, C ;
Millange, F .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225