Et2Zn as a base:: zinc enolate free from other metals significantly enhances the enantiomeric excess in palladium-catalyzed allylic alkylation

被引：31

作者：

Fuji, K ^{[1
]}

Kinoshita, N

Tanaka, K

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

[2] Univ Shizuoka, Sch Pharmaceut Sci, Shizuoka 4228526, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a906034k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enantiomeric excess of palladium-catalyzed allylic alkylations was greatly increased when Et2Zn was used as the base to generate an anion from malonates.

引用

页码：1895 / 1896

页数：2

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