Water-Soluble Polymers from Acid-Functionalized Norbornenes

被引：31

作者：

Lienkamp, Karen ^{[1
]}

Kins, Christoph F. ^{[1
]}

Alfred, Sterling F. ^{[1
]}

Madkour, Ahmad E. ^{[1
]}

Tew, Gregory N. ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2009年 / 47卷 / 05期

基金：

美国国家科学基金会;

关键词：

carboxylic acid; dynamic light scattering; norbornene; oxa-norbornene; poly electrolyte; ring-opening metathesis polymerization (ROMP); water-soluble polymers; OPENING METATHESIS POLYMERIZATION; POLY(ETHYLENE OXIDE); METAL-IONS; ROMP; COPOLYMERS; TITRATION; SYSTEMS;

D O I：

10.1002/pola.23223

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Unprotected exo,exo-5-norbornene-2,3-dicarboxylic acid and exo,exo-7-oxa-5-norbornene-2,3-dicarboxylic acid were polymerized via ring-opening metathesis polymerization. This reaction yielded polymers with molecular weights (M-n from GPC) ranging from 31 to 242 kg/mol and polydispersity indices between 1.05 and 1.12, using Grubbs' third generation catalyst. The water solubility as a function of pH value of the polymers was investigated by dynamic light scattering (DLS). DLS and acid-base titration revealed that the oxanorbornene polymer was water soluble over a wider pH range than its norbornene analog. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1266-1273, 2009

引用

页码：1266 / 1273

页数：8

共 30 条

[1] Polydispersity control in ring opening metathesis polymerization of amphiphilic norbornene diblock copolymers [J].