Investigation into the ROMP copolymerization of peptide- and PEG-functionalized norbornene derivatives

被引：51

作者：

Biagini, Stefano C. G. ^{[1
]}

Parry, Alison L. ^{[1
]}

机构：

[1] Univ Kent, Sch Phys Sci, Chem Lab, Funct Mat Grp, Canterbury CT2 7NR, Kent, England

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2007年 / 45卷 / 15期

关键词：

copolymerization; peptides; poly(vinyl ethers); ROMP;

D O I：

10.1002/pola.22068

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The ring-opening metathesis polymerizations (ROMP), using RuCl2 (PCY3)(2)CHPh, of a series of peptide-functionalized norbornene derivatives have been investigated. Incorporation of a PEG-monomer was found to prevent premature precipitation of polymer strands during the course of polymerization reactions and yield water compatible polymers in high conversions. (c) 2007 Wiley Periodicals, Inc.

引用

页码：3178 / 3190

页数：13

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