Small-angle neutron scattering study of the structure of superswollen micelles formed by a highly asymmetric poly(oxybutylene)-poly(oxyethylene) diblock copolymer in aqueous solution

被引:22
作者
Castelletto, V [1 ]
Hamley, IW
Pedersen, JS
机构
[1] Univ Leeds, Dept Chem, Leeds LS2 9JT, W Yorkshire, England
[2] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark
关键词
D O I
10.1021/la036231b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure and packing of micelles of diblock B20E610 were investigated using small-angle neutron scattering (SANS) experiments. Detailed information on chain conformation was obtained as a function of the temperature and composition. Density profiles of the model polymer brush" corona chains were obtained."
引用
收藏
页码:2992 / 2994
页数:3
相关论文
共 31 条
[11]   Structure of (deuterated PEO) (PPO) (deuterated PEO) block copolymer micelles as determined by small angle neutron scattering [J].
Goldmints, I ;
Yu, GE ;
Booth, C ;
Smith, KA ;
Hatton, TA .
LANGMUIR, 1999, 15 (05) :1651-1656
[12]   Small-angle neutron scattering study of PEO-PPO-PEO micelle structure in the unimer-to-micelle transition region [J].
Goldmints, I ;
vonGottberg, FK ;
Smith, KA ;
Hatton, TA .
LANGMUIR, 1997, 13 (14) :3659-3664
[13]   From hard spheres to soft spheres: The effect of copolymer composition on the structure of micellar cubic phases formed by diblock copolymers in aqueous solution [J].
Hamley, IW ;
Daniel, C ;
Mingvanish, W ;
Mai, SM ;
Booth, C ;
Messe, L ;
Ryan, AJ .
LANGMUIR, 2000, 16 (06) :2508-2514
[14]   Aqueous solutions and gels of diblock copolymers of 1,2-butylene oxide and ethylene oxide studied by light scattering and rheology [J].
Kelarakis, A ;
Havredaki, V ;
Viras, K ;
Mingvanish, W ;
Heatley, F ;
Booth, C ;
Mai, SM .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (31) :7384-7393
[15]  
King SM, 1997, MACROMOLECULES, V30, P6215, DOI 10.1021/ma9706236
[16]   HARD-SPHERE INTERACTIONS BETWEEN SPHERICAL DOMAINS IN DIBLOCK COPOLYMERS [J].
KINNING, DJ ;
THOMAS, EL .
MACROMOLECULES, 1984, 17 (09) :1712-1718
[17]   Star polymers viewed as ultrasoft colloidal particles [J].
Likos, CN ;
Lowen, H ;
Watzlawek, M ;
Abbas, B ;
Jucknischke, O ;
Allgaier, J ;
Richter, D .
PHYSICAL REVIEW LETTERS, 1998, 80 (20) :4450-4453
[18]  
Lindner P, 2002, N-HOLLAND D, P23
[19]   Small-angle neutron scattering analysis of the structure and interaction of triblock copolymer micelles in aqueous solution [J].
Liu, YC ;
Chen, SH ;
Huang, JS .
MACROMOLECULES, 1998, 31 (07) :2236-2244
[20]   Interaction and percolation in the L64 triblock copolymer micellar system [J].
Lobry, L ;
Micali, N ;
Mallamace, F ;
Liao, C ;
Chen, SH .
PHYSICAL REVIEW E, 1999, 60 (06) :7076-7087