A microporous metal-organic framework for gas-chromatographic separation of alkanes

被引:1155
作者
Chen, BL [1 ]
Liang, CD
Yang, J
Contreras, DS
Clancy, YL
Lobkovsky, EB
Yaghi, OM
Dai, S
机构
[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78541 USA
[2] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[3] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA
[4] Cornell Univ, Baker Lab, Dept Chem & Biol Chem, Ithaca, NY 14853 USA
关键词
alkanes; gas chromatography; metal-organic frameworks; microporous materials; sorption;
D O I
10.1002/anie.200502844
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Filling the pores: A zinc-based metal-organic framework (MOF) can be transformed reversibly from an open (a) to a dense (b) configuration. The microporous solid is the first example of a MOF that is highly selective in the gas-chromatographic separation of alkanes. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1390 / 1393
页数:4
相关论文
共 50 条
  • [21] Chiral porous hybrid solids for practical heterogeneous asymmetric hydrogenation of aromatic ketones
    Hu, AG
    Ngo, HL
    Lin, WB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (38) : 11490 - 11491
  • [22] Engineering coordination polymers towards applications
    Janiak, C
    [J]. DALTON TRANSACTIONS, 2003, (14) : 2781 - 2804
  • [23] Functional porous coordination polymers
    Kitagawa, S
    Kitaura, R
    Noro, S
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) : 2334 - 2375
  • [24] Porous coordination-polymer crystals with gated channels specific for supercritical gases
    Kitaura, R
    Seki, K
    Akiyama, G
    Kitagawa, S
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (04) : 428 - 431
  • [25] Kitaura R, 2002, ANGEW CHEM INT EDIT, V41, P133, DOI 10.1002/1521-3773(20020104)41:1<133::AID-ANIE133>3.0.CO
  • [26] 2-R
  • [27] Kitaura R., 2002, ANGEW CHEM, V114, P141, DOI DOI 10.1002/1521-3757(20020104)114:1
  • [28] Kitaura R., 2003, ANGEW CHEM, V115, P444
  • [29] Kulprathipanja S., 1984, U.S. patent, Patent No. [4,445,444, 4445444, 4 445444]
  • [30] Lee E. Y., 2004, ANGEW CHEM, V116, P2858