Vapor-liquid equilibrium for binary systems of carbon dioxide plus methanol, hydrogen plus methanol, and hydrogen plus carbon dioxide at high pressures
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Bezanehtak, K
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机构:Univ New S Wales, Sch Chem Engn & Ind Chem, Sydney, NSW 2052, Australia
Bezanehtak, K
Combes, GB
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机构:Univ New S Wales, Sch Chem Engn & Ind Chem, Sydney, NSW 2052, Australia
Combes, GB
Dehghani, F
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机构:Univ New S Wales, Sch Chem Engn & Ind Chem, Sydney, NSW 2052, Australia
Dehghani, F
Foster, NR
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Univ New S Wales, Sch Chem Engn & Ind Chem, Sydney, NSW 2052, AustraliaUniv New S Wales, Sch Chem Engn & Ind Chem, Sydney, NSW 2052, Australia
Foster, NR
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Tomasko, DL
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机构:Univ New S Wales, Sch Chem Engn & Ind Chem, Sydney, NSW 2052, Australia
Tomasko, DL
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[1] Univ New S Wales, Sch Chem Engn & Ind Chem, Sydney, NSW 2052, Australia
[2] Ohio State Univ, Dept Chem Engn, Columbus, OH 43210 USA
Vapor-liquid equilibrium data and density of the liquid phase for binary systems of carbon dioxide + methanol, hydrogen + methanol, and carbon dioxide + hydrogen at high pressures were determined. A dynamic technique with liquid-phase recirculation and on-line gas chromatography was used in this study. The equilibrium data and density were measured at temperatures between 278.15 K and 308.15 K, and pressures between 15 bar and 192.53 bar. The isothermal volume expansion behavior for the carbon dioxide + methanol system at various temperatures was also determined.