Rotational-state selective nuclear magnetic resonance spectra of hydrogen in a molecular trap

被引：20

作者：

Tomaselli, M ^{[1
]}

Meier, BH ^{[1
]}

机构：

[1] ETH Zurich, Phys Chem Lab, CH-8093 Zurich, Switzerland

来源：

JOURNAL OF CHEMICAL PHYSICS | 2001年 / 115卷 / 24期

关键词：

D O I：

10.1063/1.1429655

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A nuclear magnetic resonance (NMR) study of the molecular quantum dynamics of hydrogen trapped in solid C-60 is presented. Rotational-state selective NMR spectra are shown. The analysis of the spectra provides a direct map of the molecular orientational probability distribution and of the rotational wave functions. Perturbations of the free rotor behavior due to rotor-phonon interactions and due to the S-6 symmetry of the confining cage potential are discussed. (C) 2001 American Institute of Physics.

引用

页码：11017 / 11020

页数：4

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