Chirality-controlled and solvent-templated catenation isomerism in metal-organic frameworks

被引：255

作者：

Ma, Liqing ^{[1
]}

Lin, Wenbin ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 42期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ja804944r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A family of highly porous homochiral, racemic, and meso metal-organic frameworks (MOFs) were synthesized based on a new elongated tetra-carboxylate ligand and the copper paddle-wheel building units. These MOFs exhibited remarkable catenation isomerism that is controlled by both chirality of the bridging ligand and the size of solvent molecules. The ability to manipulate framework interpenetration is key to future synthesis os mesoporous homochiral MOFs which hold great promise in heterogeneous asymmetric catalysis and chiral separations.

引用

收藏

页码：13834 / 13835

页数：2

相关论文

共 22 条

[1]

Bradshaw D, 2007, SCIENCE, V315, P977, DOI 10.1126/science1135445

[2] Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal-organic framework material [J].

Chen, Banglin ;

Zhao, Xuebo ;

Putkham, Apipong ;

Hong, Kunlun ;

Lobkovsky, Emil B. ;

Hurtado, Eric J. ;

Fletcher, Ashleigh J. ;

Thomas, K. Mark .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) :6411-6423

[3] A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation [J].

Cho, So-Hye ;

Ma, Baoqing ;

Nguyen, SonBinh T. ;

Hupp, Joseph T. ;

Albrecht-Schmitt, Thomas E. .

CHEMICAL COMMUNICATIONS, 2006, (24) :2563-2565

[4] A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity [J].

Dybtsev, DN ;

Nuzhdin, AL ;

Chun, H ;

Bryliakov, KP ;

Talsi, EP ;

Fedin, VP ;

Kim, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :916-920

[5] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[6] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

[7] Mesoporous metal-organic framework with rare etb topology for hydrogen storage and dye assembly [J].

Fang, Qian-Rong ;

Zhu, Guang-Shan ;

Jin, Zhao ;

Ji, Yan-Yan ;

Ye, Jun-Wei ;

Xue, Ming ;

Yang, Hua ;

Wang, Yue ;

Qiu, Shi-Lun .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (35) :6638-6642

[8] Crystallized frameworks with giant pores:: Are there limits to the possible? [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225

[9] Enantiopure vs. racemic metalloligands:: impact on metal-organic framework structure and synthesis [J].

Garibay, Sergio J. ;

Stork, Jay R. ;

Wang, Zhenqiang ;

Cohen, Seth M. ;

Telfer, Shane G. .

CHEMICAL COMMUNICATIONS, 2007, (46) :4881-4883

[10] New approaches to the analysis of high connectivity materials:: Design frameworks based upon 44- and 63-subnet tectons [J].

Hill, RJ ;

Long, DL ;

Champness, NR ;

Hubberstey, P ;

Schröder, M .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :335-348