Molecular tectonics:: coordination networks based on porphyrins bearing pyridine N-oxide groups as coordinating sites

被引：20

作者：

Deiters, E ^{[1
]}

Bulach, V ^{[1
]}

Kyritsakas, N ^{[1
]}

Hosseini, MW ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, UMR 7140, Chim Coordinat Organ Lab, F-67000 Strasbourg, France

来源：

NEW JOURNAL OF CHEMISTRY | 2005年 / 29卷 / 12期

关键词：

D O I：

10.1039/b511049c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of the two positional isomers 1 and 2, porphyrin backbones bearing two pyridine N-oxide groups (PNO), with Zn(II) cations leads to 1-Zn and 2-Zn self-complementary tectons which generate in the crystalline phase analogous 1-D zigzag type coordination networks with different metrics. In both cases, only one PNO group bridges the consecutive tecton through coordination to the Zn atom which adopts the square based pyramidal geometry.

引用

页码：1508 / 1513

页数：6

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