Reversible single-crystal-to-single-crystal guest exchange in a 3-D coordination network based on a zinc porphyrin

被引:119
作者
Deiters, E [1 ]
Bulach, V [1 ]
Hosseini, MW [1 ]
机构
[1] Univ Strasbourg, Chim Coordinat Organ Lab, UMR 7140, CNRS, F-67000 Strasbourg, France
关键词
D O I
10.1039/b508135c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A self-complementary tecton based on a zinc porphyrin core bearing two pyridines at the opposite meso positions leads to the formation of a 3-D coordination network in the crystalline phase which offers channels which are filled with solvent molecules; reversible exchange of the guest molecules has been proven to take place in a single-crystal-to-single-crystal type transformation demonstrating the robustness of the coordination framework.
引用
收藏
页码:3906 / 3908
页数:3
相关论文
共 30 条
[1]   ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].
ABRAHAMS, BF ;
HOSKINS, BF ;
MICHAIL, DM ;
ROBSON, R .
NATURE, 1994, 369 (6483) :727-729
[2]   Design, chirality, and flexibility in nanoporous molecule-based materials [J].
Bradshaw, D ;
Claridge, JB ;
Cussen, EJ ;
Prior, TJ ;
Rosseinsky, MJ .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282
[3]   Four new 2D porous polymeric frames from the self-assembly of silver triflate and silver tosylate with free-base and Zn-metallated 5,10,15,20-tetra(4-pyridyl)porphyrin [J].
Carlucci, L ;
Ciani, G ;
Proserpio, DM ;
Porta, F .
CRYSTENGCOMM, 2005, 7 :78-86
[4]   A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].
Chui, SSY ;
Lo, SMF ;
Charmant, JPH ;
Orpen, AG ;
Williams, ID .
SCIENCE, 1999, 283 (5405) :1148-1150
[5]   Design, synthesis and structural studies on polynucleating ligands based on atropoisomerism of catechol bearing porphyrins [J].
Drexler, C ;
Hosseini, MW ;
Planeix, JM ;
Stupka, G ;
De Cian, A ;
Fischer, J .
CHEMICAL COMMUNICATIONS, 1998, (06) :689-690
[6]   Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].
Eddaoudi, M ;
Moler, DB ;
Li, HL ;
Chen, BL ;
Reineke, TM ;
O'Keeffe, M ;
Yaghi, OM .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330
[7]   Crystallized frameworks with giant pores:: Are there limits to the possible? [J].
Férey, G ;
Mellot-Draznieks, C ;
Serre, C ;
Millange, F .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225
[8]   Crystal engineering of porphyrin framework solids [J].
Goldberg, I .
CHEMICAL COMMUNICATIONS, 2005, (10) :1243-1254
[9]   In situ single-crystal X-ray diffraction studies of desorption and sorption in a flexible nanoporous molecular framework material [J].
Halder, GJ ;
Kepert, CJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (21) :7891-7900
[10]   Metric engineering of soft molecular host frameworks [J].
Holman, KT ;
Pivovar, AM ;
Swift, JA ;
Ward, MD .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (02) :107-118